ペロブスカイト・有機ポリマー材料
Solaris Chem ペロブスカイト材料
ペロブスカイト材料は、その優れた光電子特性により、近年、特に太陽光発電の分野で大きな注目を集めています。その他用途として、LED、光検出器、レーザー、センサー等に注目されています。
Perovskite前駆体
| Product Code | Product Name | Notes |
|---|---|---|
| SV001 CH6IN | Methylammonium iodide Methylamine hydroiodide | CAS# 14965-49-2 Purity: >99.99 % Color and Texture: White powder Molecular Weight: 158.97 g/mol Absorption, λmax (Media): N/A |
| SV002 CH6BrN | Methylammonium bromide | CAS# 6876-37-5 Purity: >99.99 % Color and Texture: White powder Molecular Weight: 111.97 g/mol Absorption, λmax (Media): N/A |
| SV003 CH5IN2 | Formamidinium iodide | CAS# 879643-71-7 Purity: >99.99 % Color and Texture: White powder Molecular Weight: 171.97 g/mol Absorption, λmax (Media): N/A |
| SV004 CH5BrN2 | Formamidinium bromide | CAS# 146958-06-7 Purity: >99.99 % Color and Texture: White powder Molecular Weight: 124.97 g/mol Absorption, λmax (Media): N/A |
Perovskite太陽電池正孔輸送材料
| Product Code | Product Name | Notes |
|---|---|---|
| SOL2426 Low Mw: 5–20kDa(SOL2426L) Medium Mw: 20–75kDa(SOL2426M) High Mw: 75–200kDa(SOL2426H) Ultra-High Mw: 200–500kDa(SOL2426UH) | PTAA Poly[bis(4-phenyl)(2,4,6-trimethylphenyl)amine] | CAS# 1333317-99-9 Color and Texture: Pale yellow / powder Molecular Weight: N/A Absorption, λmax (Media): N/A Emission, λmax (Media): N/A HOMO (eV): 5.25eV LUMO (eV): 2.30eV Decomposition Temperature (°C): 502 °C (under inert atmosphere) Solubility (Solvent): THF, Toluene, oDCB Other |
| SOL2446 Low Mw: 5–20kDa(SOL2446L) Medium Mw: 20–50kDa(SOL2446M) Medium-High Mw: 50–100kDa(SOL2446MH) High Mw: 100–200kDa(SOL2446H) | Fluoro-PTAA Poly[bis(4-phenyl)(4-fluoro-2-methylphenyl)amine] | CAS# N/A Color and Texture: Pale yellow / powder Molecular Weight: N/A Absorption, λmax (Media):372 nm Emission, λmax (Media): N/A HOMO (eV): −5.52 eV LUMO (eV): −2.55 eV Decomposition Temperature (°C): 522 °C (under inert atmosphere) Solubility (Solvent): THF, Toluene, o-DCB Eg (optd): 2.97 eV |
Perovskite太陽電池ポリマー
| Product Code | Product Name | Notes |
|---|---|---|
| POL2426 Mw:5K–1000k | PTAA batch larger quantities | CAS# 1333317-99-9 Color and Texture: Pale yellow / powder Molecular Weight: N/A Absorption, λmax (Media):N/A Emission, λmax (Media): N/A HOMO (eV):5.25eV LUMO (eV):2.30eV Decomposition temperature:502 °C (under inert atmosphere) Solubility (Solvent): THF, Toluene, oDCB |
| SOL4150 Mw:30–80KDa | 12-PQT Poly(3,3”’-didodecyl quarter thiophene), Poly(3,3′′′-didodecyl[2,2′:5′,2′′:5′′,2′′′- quaterthiophene]-5,5′′′-diyl), Poly(4,n/a4′′-didodecyl[2,2′:5′,2′′:5′′,2′′′- quaterthiophene]-5,5′′′-diyl) Used as an electron Donor to Acceptor materials such as PC71BM (SOL5071) to make bulk heterojunction solar cells and mainly organic transistors. | CAS# 827343-06-6 Color and Texture: brown-reddish / solid Molecular Weight: N/A Absorption, λmax (Media): λmax 465 ± 5 nm (THF) Emission, λmax (Media): λmax 615 ± 5 nm (film) HOMO (eV): -5.24 eV LUMO (eV): -2.97 eV Melting point (°C): >200ºC Solubility (Solvent): Toluene, THF, chlorobenzene, chloroform Other: N/A Used as an electron Donor to Acceptor materials such as C70-PCBM (SOL5071) to make bulk heterojunction solar cells and mainly organic transistors. |
| SOL2529 Mw:50–250kDa | F8BT Poly[(9,9-di-n-octylfluorenyl-2,7-diyl)-alt-(benzo[2,1,3]thiadiazol-4,8-diyl)], Poly(9,9-dioctylfluorene-alt-benzothiadiazole); PFO-BT | CAS# 210347-52-7 Color and Texture: orange powder/fibers Molecular Weight: N/A Absorption, λmax (Media): N/A Emission, λmax (Media): N/A HOMO (eV): -5.9 eV LUMO (eV): 3.3 eV Melting point (°C): N/A Solubility (Solvent): Chlorobenzene, chloroform, toluene. Other: N/A Polymer for optoelectronic applications. Green emitter (529 nm in THF) for OLEDs, OFETs, and light-emitting transistors for OPVs. |
| SOL2562 Mw:25–150KDa | F8Se2 Poly[(9,9-dioctylfluorenyl-2,7-diyl)-alt-co-(biselenophene)] | CAS# N/A Color and Texture: N/A Molecular Weight: N/A Absorption, λmax (Media): N/A Emission, λmax (Media): N/A HOMO (eV): -5.4 eV LUMO (eV): -2.6 eV Melting point (°C): N/A Solubility (Solvent): Chloroform, THF, Chlorobenzene Other: N/A Polymer (p-type) for optoelectronic applications. Red Emitter (578 nm Film) for OTFT, OLED, and other applications. |
| SOL2552 Mw:25–150KDa | F8T2 PFOT, Poly(9,9-dioctylfluorene-alt-bithiophene), Poly[(9,9-dioctylfluorenyl-2,7-diyl)-co-bithiophene] | CAS# 210347-56-1 Color and Texture: yellow / powder Molecular Weight: N/A Absorption, λmax (Media): λmax 454 ± 5 nm (THF) Emission, λmax (Media): λmax 495 ± 5 nm (THF) HOMO (eV): 5.5 eV LUMO (eV): 3.1 eV Melting point (°C): N/A Solubility (Solvent): Chloroform, chlorobenzene or dichlorobenzene Other: N/A Semiconducting material that is widely used in organic electronics such as organic photovoltaics, polymer light-emitting diodes (PLED) and organic field-effect transistors (OFETs). |
| SOL2426 Low Mw:5–20kDa (SOL2426L) Medium Mw:20–75kDa (SOL2426M) High Mw:75–200kDa (SOL2426H) Ultra-High Mw:200–500kDa (SOL2426UH) | PTAA Poly[bis(4-phenyl)(2,4,6-trimethylphenyl)amine] | CAS# 1333317-99-9 Color and Texture: Pale yellow / powder Molecular Weight: N/A Absorption, λmax (Media): N/A Emission, λmax (Media): N/A HOMO (eV): 5.25eV LUMO (eV): 2.30eV Decomposition Temperature (°C): 502 °C (under inert atmosphere) Solubility (Solvent):THF, Toluene, oDCB Other |
| SOL2446 Low Mw:5–20kDa (SOL2446L) Medium Mw:20–50kDa (SOL2446M) Medium-High Mw:50–100kDa (SOL2446MH) High Mw:100–200kDa (SOL2446H) | Fluoro-PTAA Poly[bis(4-phenyl)(4-fluoro-2-methylphenyl)amine] | CAS# N/A Color and Texture: Pale yellow / powder Molecular Weight: N/A Absorption, λmax (Media): 372 nm Emission, λmax (Media): N/A HOMO (eV):−5.52 eV LUMO (eV):−2.55 eV Decomposition Temperature (°C): 522 °C (under inert atmosphere) Solubility (Solvent):THF, Toluene, o-DCB Eg (optd):2.97 eV Poly[bis(4-phenyl)(4-fluoro-2-methylphenyl)amine is one of the family members of poly(triaryl)amine, closely related to PTAA but with a deeper HOMO energy level of −5.52 eV (vs −5.14 eV for PTAA). Excellent semiconductor material that transports holes and blocks electrons due to its electron-rich components. The use of this polymer can significantly improve the open-circuit voltage (VOC) and the fill factor (FF) of the cells in high-performance perovskite solar cells. Fluoro-PTAA can be coated as a substrate material used for hole transport in the manufacture of many devices such as perovskite solar cells, organic light-emitting diodes (OLED) and organic field-effect transistors. |
| SOL4106 Mw = 70-90 kD, low pdi – P3HT RR 90-95% (SOL4106A) Mw = 50-70 kD, low pdi – P3HT RR 87-92% (SOL4106B) Mw = 30-50 kD, low pdi – P3HT RR-87-92% (SOL4106C) | P3HT Poly(3-hexylthiophene-2,5-diyl) | CAS# 104934-50-1 Color and Texture: dark brown, solid powder Molecular Weight: N/A Absorption, λmax (Media):N/A Emission, λmax (Media): N/A HOMO (eV):-5.2 eV LUMO (eV):-3.2 eV Melting point (°C):N/A Solubility (Solvent): Chloroform, chlorobenzene Other: N/A P3HT (poly(3-hexylthiophene-2,5-diyl) is a p-type conductive polymer chain that is currently one of the most widely used materials in photovoltaics due to its interesting electronic properties. One of the most studied applications of P3HT is the development of organic photovoltaic cells with heterojunctions, which are produced in solution because they are light, flexible, and inexpensive to manufacture. These cells are developed using a mixture of (poly(3-hexylthiophene) and phenyl-C61-butyric acid methyl ester (P3HT:PCBM). We offer three grades with different molecular weights for a variety of research purposes. |
| SOL4720 Mw: 100–250kDa | PBDTTT-EFT ; PCE-10 ; PTB7-Th Poly({4,8-bis[(4-(2-ethylhexyl) thiophen-2-yl)]benzo[1,2-b:4,5-b′]dithiophene-2,6-diyl}{3-fluoro-2-[(2-ethylhexyl)carbonyl]thieno[3,4-b]thiophenediyl}) | CAS# 1469791-66-9 Color and Texture: Solid dark brown powder Molecular Weight: N/A Absorption, λmax (Media): N/A Emission, λmax (Media): N/A HOMO (eV): 5.24eV LUMO (eV): 3.66eV Melting point (°C): N/A Solubility (Solvent): Chlorobenzene, dichlorobenzene Other: N/A Low Bandgap polymer for optoelectronic applications. Can be used with PCBMs (SOL5061 or SOL5071) to make >10% PCE Solar Cells using. |
Solaris Chem Polymers 有機薄膜太陽電池向けポリマー
| Product Code | Product Name | Notes |
|---|---|---|
| PTB7 | Poly({4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b’]dithiophene-2,6-diyl}{3-fluoro-2-[(2-ethylhexyl)carbonyl]thieno[3,4-b]thiophenediyl}) | Typical Mw = 50-100kDa Typical Mw = 100-250kDa |
| PBDTTT-EFT | Poly({4,8-bis[(4-(2-ethylhexyl)thiophen-2-yl)]benzo[1,2-b:4,5-b′]dithiophene-2,6-diyl}{3-fluoro-2-[(2-ethylhexyl)carbonyl]thieno[3,4-b]thiophenediyl})-PCE-10 | Typical Mw = 100-250kDa |
| PDCBT | poly[(4,4′-bis(2-butyloctoxycarbonyl-[2,2′-bithiophene]-5,5-diyl)-alt-(2,2′-bithiophene-5,5′-diyl)][ | Typical Mw = 30-80 kDa |
| P3HT | Poly(3-hexylthiophene)-regioregular,electronic grade | Typical Mw = 50-90 kDa, PD = 1.4-1.9 |
| PTEBS | Poly[2-(3-thienyl)ethyloxy-4-butylsulfonate] sodium salt | Typical Mw = 40-70 kDa |
| 12PQT | Poly(3,3”’-didodecyl quarterthiophene) | Typical Mw = 30-80 kDa |
| poly-TPD | Poly[N,N’-bis(4-butylphenyl)-N,N’-bis(phenyl)- benzidine] | Low Mw: 10-30 kDa Medium Mw: 30-100 kDa High Mw: 100-250 kDa Ultra High Mw: 250-500 kDa |
| poly-TPD-C6 | Poly[N,N’-bis(4-hexylphenyl)-N,N’-bis(phenyl)- benzidine] | Low Mw: 5-20 kDa Medium Mw: 20-75 kDa High Mw: 75-200 kDa Ultra High Mw: 200-500 kDa |
| poly-TPD-C8 | Poly[N,N’-bis(4-hexylphenyl)-N,N’-bis(phenyl)- benzidine] | Low Mw: 5-20 kDa Medium Mw: 20-75 kDa High Mw: 75-200 kDa Ultra High Mw: 200-500 kDa |
| PTAA | Poly(triaryl amine)Poly[bis(4-phenyl)(2,4,6-trimethylphenyl)amine] | Low Mw: 5-20 kDa Medium Mw: 20-75 kDa High Mw: 75-200 kDa Ultra High Mw: 200-500 kDa |
| TFB (n-Butyl) | Poly[(9,9-dioctylfluorenyl-2,7-diyl)-co-(4,4′-(N-(4-nbutylphenyl)diphenylamine)] | Typical Mw = 5-25 kDa Typical Mw = 30-65 kDa Typical Mw = 70-125 kDa |
| TFB (sec-Butyl) | Poly[(9,9-dioctylfluorenyl-2,7-diyl)-co-(4,4′-(N-(4-secbutylphenyl)diphenylamine)] | Typical Mw = 5-25 kDa Typical Mw = 30-65 kDa Typical Mw = 70-125 kDa |
| DM-TFB | Poly[(9,9-dioctylfluorenyl-2,7-diyl)-co-(4,4′-(N-(2,4-dimethylphenyl)diphenylamine)] | Typical Mw = 20-50 kDa |
| iPrCN (iPrCN-TFB) | Poly[(9,9-dioctylfluorenyl-2,7-diyl)-co-((4,4’-(N-(diphenylamine))-(2-cyanoisopropylphenyl))] | Typical Mw = 25-50 kDa |
| PCPDTBT | Poly[2,6-(4,4-bis-(2-ethylhexyl)-4H-cyclopenta [2,1-B;3,4-B’] dithiophene)-alt-4,7(2,1,3-benzothiadiazole)] | Typical Mw = 25-60 kDa pd 1.1 – 1.4 |
| Si-PCPDTBT (PSBTBT) | Poly[2,1,3-benzothiadiazole-4,7-diyl[4 ,4-bis(2-ethylhexyl)-4Hsilolo[3,2-b:4, 5-b’]dithiophene-2,6-diyl]] | Typical Mw = 30-60 kDa4 |
| F8BT | Poly[(9,9-dioctylfluorenyl-2,7-diyl)-alt-co-(1,4-benzo-{2,1’,3}-thiadiazole)] | Typical Mw = 50-250 kDa |
| PCDTBT | Poly[N-9′-heptadecanyl-2,7-carbazole-alt-5,5-(4′,7′-di-2-thienyl-2′,1′,3′-benzothiadiazole)] | Typical Mw = Low range, 20-45 KDa (THF extract) High range, 65-85 KDa (oDCB extract) |
| PCPDTTBTT | Poly[2,6-(4,4-bis(2-ethylhexyl)-4H-cyclopenta-[2,1-b:3,4-b’]dithiophene-alt-4,7-bis(thiophen-2-yl)benzo-2,1,3-thiadiazole] | Typical Mw = 20-40 kDa |
| PFOTBT | Poly[2,7-(9,9-di-octyl-fluorene)-alt-4,7-bis(thiophen-2-yl)benzo-2,1,3-t hiadiazole] | Typical Mw = 50-80 kDa |
| F8T2 | Poly[(9,9-dioctylfluorenyl-2,7-diyl)-alt-co-(bithiophene)] | Typical Mw = 25-150 kDa |
| F8Se2 | Poly[(9,9-dioctylfluorenyl-2,7-diyl)-alt-co-(biselenophene)] | Typical Mw = 25-150 kDa HOMO: -5.4 eV LUMO: -2.6 eV |
| PFO | Poly(9,9-di-n-octylfluorenyl-2,7-diyl) | Typical Mw = 50-200 kDa Pale yellow fibers |
| PFN-DOF | Poly[(9,9-di(2,2’-N,N’-dimethylamine) propyl fluorenyl-2,7-diyl)- alt-co-(9,9-dioctyl fluorenyl-2,7-diyl)] | Typical Mw = 25-250 kDa |
| PFNI-DOF | Poly[(9,9-di(3,3’-N,N’-trimethylammonium)propyl fluorenyl-2,7-diyl)- alt-co-(9,9-dioctylfluorenyl-2,7-diyl)] diiodide salt | Typical Mw = 25-250 kDa |
| PFN | Poly[(9,9-di(2,2’-N,N’-dimethylamine)propyl fluorenyl-2,7-diyl)- alt-co-(1,4-phenylene)] | Typical Mw = 15-50 kDa |
| PFN (B) | Poly(9,9-di(2,2’-N,N’-dimethylamine) propylfluorenyl-2,7-diyl) | Typical Mw = 15-50 kDa |
| PFN-I | Poly[(9,9-di(3,3’-N,N’-trimethylammonium)propyl fluorenyl-2,7-diyl)- alt-co-(1,4-phenylene)] diiodide salt | Typical Mw = 15-50 kDa Water and alcohol Soluble |
| PFNI (diiodine salt) | Poly(9,9-di(3,3’-N,N’-trimethylammonium)propyl fluorenyl-2,7-diyl) diiodide salt | Typical Mw = 15-40 kDa |
| PFN-BT | Poly[(9,9-di(2,2’-N,N’-dimethylamine) propyl fluorenyl-2,7-diyl)- alt-co-(1,4-benzo-{2,1’,3}- thiadiazole)] | Typical Mw = 15-40 kDa |
| PFNI-BT (diiodine salt) | Poly[(9,9-di(3,3’-N,N’-trimethylammonium)propyl fluorenyl-2,7-diyl)- alt-co-(1,4-benzo-{2,1’,3}- thiadiazole)] diiodidesalt | Typical Mw = 15-40 kDa |
| PFO-MEH-PPV | Poly[(9,9-dioctyl-2,7-divinylenefluorenylene)-alt-co-{2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylene}] | Typical Mw = 20-300 kDa |
| MEH-PPV | Poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene]- End Capped withDMB | Typical Mw = 100-300 kDa |
1-Material ペロブスカイト Perovskite Hybrid Solar Cell
| 1M No. | CAS No./Formula | Chemica Name | Specification |
|---|---|---|---|
| IT0492 | 14965-49-2 CH3NH3I(MAI) | Methylammonium iodide | Crystal |
| IT0375 | 6876-37-5 CH3NH3Br (MABr) | Methylammonium bromide | White flake |
| IT0511 | 593-51-1 CH3NH3Cl (MACl) | Methylammonium chloride | White flake |
| IT0717 | 879643-71-7 (FAI) | Formamidinium iodide | White Powder |
| IT0067 | 146958-06-7 (FABr) | Formamidinium bromide | White crystal |
| IT0333 | 6313-33-3 (FACl) | Formamidinium chloride | White crystal |
| IT0917 | 45579-91-7 (BzAI) | Benzylammonium iodide | White crystal |
| IT0407 | 37488-40-7 (BzABr) | Benzylammonium bromide | White crystal |
| IT0998 | 3287-99-8 (BzACl) | Benzylammonium chloride | White crystal |
| IT0081 | 36945-08-1 (BAI) | n-Butylammonium iodide | Beige particle |
| IT0096 | 15567-09-6 (BABr) | n-Butylammonium bromide | Beige particle |
| IT0784 | 3858-78-4 (BACl) | n-Butylammonium chloride | Beige particles |
Cobalt Complex [Limited Release]
| 1M No. | CAS No. | Common Name/Chemical Name | Formula |
|---|---|---|---|
| OS0703 | 1346416-70-3 | FK102-Co(III) Cobalt(3+), tris[2-(1H-pyrazol-1-yl-κN2)pyridine-κN]-, (OC-6-22)- | C24 H21 Co N9 |
| OS0689 | 1392221-68-9 | FK102-Co(II) Cobalt(3+), tris[2-(1H-pyrazol-1-yl-κN2)pyridine-κN]-, (OC-6-22)- | C24 H21 Co N9 |
| OS0714 | 1346416-71-4 | FK102Co(III) PF6 salt Cobalt(3+), tris[2-(1H-pyrazol-1-yl-κN2)pyridine-κN]-, (OC-6-22)-,hexafluorophosphate(1-) (1:3) | C24 H21 Co N9 . 3 F6 P |
| OS0690 | 1392221-69-0 | FK102Co(II) PF6 salt Cobalt(2+), tris[2-(1H-pyrazol-1-yl-κN2)pyridine-κN]-, (OC-6-22)-,hexafluorophosphate(1-) (1:2) | C24 H21 Co N9 . 2 F6 P |
| OS1033 | na | FK102Co(III) TFSI salt Cobalt(3+), tris[2-(1H-pyrazol-1-yl-κN2)pyridine-κN]- salt with 1,1,1-trifluoro-N- [(trifluoromethyl)sulfonyl]methanesulfonamide (1:3) | C24 H21 Co N9 ·3C2 F6 N O4 S2 |
| OS1022 | na | FK102Co(II) TFSI salt Cobalt(2+), tris[2-(1H-pyrazol-1-yl-κN2)pyridine-κN]- salt with 1,1,1-trifluoro-N- [(trifluoromethyl)sulfonyl]methanesulfonamide (1:2) | C24 H21 Co N9 ·3C2 F6 N O4 S2 |
| OS0615 | 1447938-61-5 | FK209 Tris(2-(1H-pyrazol-1-yl)-4-tert-butyl pyridine)cobalt(III) Tris(bis(trifluoromethylsulfonyl)imide)) | C36 H45 Co N9 . 3 C2 F6 N O4 S2 |
| OS0637 | 1447938-63-7 | FK269 Cobalt(3+), bis[2,6-di(1H-pyrazol-1-yl-κN2)pyridine- κN]-, (OC-6-11′)-, salt with 1,1,1-trifluoro-N- [(trifluoromethyl)sulfonyl]methanesulfonamide (1:3) | C22 H18 Co N10 . 3 C2 F6 N O4 S2 |